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反相微乳液制备AgCl/PMMA复合胶乳及其抗菌性能

陈甜甜 李娜 祝方琦 孙志轩 吴礼光

高校化学工程学报Issue(2):381-386,6.
高校化学工程学报Issue(2):381-386,6.DOI:10.3969/j.issn.1003-9015.2015.02.021

反相微乳液制备AgCl/PMMA复合胶乳及其抗菌性能

Preparation of AgCl/PMMA Latex via W/O Microemulsion and its Antibacterial Activity

陈甜甜 1李娜 1祝方琦 1孙志轩 1吴礼光1

作者信息

  • 1. 浙江工商大学环境科学与工程学院,浙江杭州 310012
  • 折叠

摘要

Abstract

Composites containing silver halide nanoparticles have attracted great interest as potential antibacterial materials. AgCl nanoparticles were synthesized in W/O microemulsion using octylphenylpolyethylene glycol (OP) as the emulsifier and methyl methacrylate (MMA) as the oil phase. AgCl/PMMA complex latex was prepared via in situ microemulsion polymerization. Effects of surfactant (cOP) and salt (csalt) concentration on the formation and morphology of AgCl nanoparticles were studied by ultraviolet-visible spectrum and transmission electron microscopy (TEM). Furthermore, the antibacterial effect of AgCl/PMMA latex was evaluated againstE. coli. The results show that the AgCl nanoparticles prepared were spherical with a mean diameter of about 5 nm. The increase ofcOPandcsalt promotes the formation of AgCl nanoparticles with smaller diameter in the W/O microemulsion, which provide the AgCl/PMMA latex good antibacterial activity. This simple and mild preparation method can be easily applied in an industrial scale process. Therefore, the AgCl/PMMA latex prepared is a novel antibacterial latex with great potentially applications.

关键词

聚乙二醇辛基苯基醚/反相微乳液/AgCl纳米粒子/AgCl/PMMA复合胶乳/抗菌性能

Key words

octylphenylpolyethylene glycol/W/O microemulsion/AgCl nanoparticles/AgCl/PMMA latex/antibacterial activity

分类

化学化工

引用本文复制引用

陈甜甜,李娜,祝方琦,孙志轩,吴礼光..反相微乳液制备AgCl/PMMA复合胶乳及其抗菌性能[J].高校化学工程学报,2015,(2):381-386,6.

基金项目

国家自然科学基金(20876144,21076190,21376218)。 (20876144,21076190,21376218)

高校化学工程学报

OA北大核心CSCDCSTPCD

1003-9015

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