海南师范大学学报(自然科学版)Issue(2):176-179,4.
基于2-(1H-四唑-5-基)吡啶配体的双核铬配合物的合成,晶体结构与红外光谱分析
Synthesis, Crystal Structure and IR Spectra of Binuclear Cr(III) Complex with 2-(1H-Tetrazol-5-yl)Pyridine Ligand
摘要
Abstract
The binuclear Cr(III)complex [Cr2(Cl)2(tzp)4](tzp=2-(1H-tetrazol-5-yl)pyridine)had been synthesized with tzp ligand and CrCl3·6H2O by solvent diffusion in H tube. The crystal structure was determined by single-crystal X-ray dif⁃fraction method. Each Cr(III)ion adopts a distorted octahedron coordination geometry with four N atoms of four tzp ligands and two Cl anion. In addition, the ligand and complex were characterized by the IR spectra, respectively.关键词
2-(1H-四唑-5-基)吡啶/铬(III)/合成/晶体结构/红外光谱Key words
2-(1H-tetrazol-5-yl)pyridine)/Cr(III)/synthesis/crystal structure/IR spectra分类
化学化工引用本文复制引用
钮智刚,陈豪华,陈亭亭,夏庆,李高楠..基于2-(1H-四唑-5-基)吡啶配体的双核铬配合物的合成,晶体结构与红外光谱分析[J].海南师范大学学报(自然科学版),2015,(2):176-179,4.基金项目
海南省自然科学基金资助项目(20152017,20152031);海南师范大学国家级大学生创新创业训练计划项目 ()