化工进展Issue(6):1486-1490,5.DOI:10.3969/j.issn.1000-6613.2014.06.021
乙炔氢氯化反应非贵金属无汞催化剂的研究进展
Research progress of mercury-free catalysts of non-noble metal for acetylene hydrochlorination
摘要
Abstract
Mercury-free catalysts for acetylene hydrochlorination have received wide attentions due to their considerable activity and environmental benefits. The research progress of mercury-free catalysts for acetylene hydrochlorination in recent years is reviewed. The main methods for improving the catalytic properties of non-noble metal catalysts and the effects of active component,support,and preparation process on catalytic activity are summarized. The relationship between catalytic activity and reaction mechanism of solid or liquid systems is presented. The conditions for the highly active, long life mercury-free catalysts of non-noble metal to be used in acetylene hydrochlorination are analyzed. Concerted catalysis of non-noble metals , various processing methods for supports , optimization of catalyst preparation,and application of ionic liquids will be the development trends of mercury-free catalysts for acetylene hydrochlorination.关键词
乙炔氢氯化/非贵金属/催化剂/载体/制备Key words
acetylene hydrochlorination/non-noble metal/catalyst/support/preparation分类
化学化工引用本文复制引用
郭燕燕,刘鹰,胡瑞生,孙宏娟..乙炔氢氯化反应非贵金属无汞催化剂的研究进展[J].化工进展,2014,(6):1486-1490,5.基金项目
国家自然科学基金项目(21266015、20806036)。 ()