化工进展Issue(8)：2199-2205,7.DOI:10.3969/j.issn.1000-6613.2014.08.044
催化臭氧分离膜制备及去除腐殖酸机理分析
Preparation of catalytic ozonation membrane and analysis of humic acid removal mechanism
摘要
Abstract
To further improve the effectiveness of membrane process and reduce membrane fouling, catalytic membranes were prepared with the phase transfer method in order to realize microfiltration coupling and catalytic ozonation for micro-polluted water treatment. The sol-gel method was used to prepare TiO2,and nano-sized particles at different heat treatment temperatures were added into the casting solution. The characteristics of catalytic membranes were investigated with X-ray diffraction (XRD),scanning electron microscopy(SEM),water flux,porosity,and contact angle. The membranes catalytic efficiency and membrane separation processes were also investigated. Rutile TiO2 (namely PVDF/ TiO2-600) membrane achieved above 70% and 65% removal rate of humic acid (HA) and total organic carbon (TOC),respectively. The novel catalytic membrane exhibited good catalytic ozonation activity and anti-fouling property for HA removal,which demonstrated that catalytic ozonation membrane an emerging technique for water treatment.关键词
催化臭氧化/纳米粒子/膜/腐殖酸/过滤Key words
catalytic ozonation/nanoparticles/membrane/humic acid/filtration分类
资源环境引用本文复制引用
张海丰,柴慧建,赵贵龙,张兰河,Song L..催化臭氧分离膜制备及去除腐殖酸机理分析[J].化工进展,2014,(8):2199-2205,7.基金项目
吉林省科技发展计划（20120404，20130206061GX）、吉林市科技支撑基金（20106306，201232403）及中国电机工程学会电力青年科技创新项目（2009NEDU）。 （）
