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离子热合成金属-有机骨架材料最新研究进展

肖冰心 刘杰 王双 井淑波

化工进展Issue(9):2363-2371,9.
化工进展Issue(9):2363-2371,9.DOI:10.3969/j.issn.1000-6613.2014.09.022

离子热合成金属-有机骨架材料最新研究进展

Advance in the ionothermal synthesis of metal-organic frameworks

肖冰心 1刘杰 1王双 1井淑波1

作者信息

  • 1. 吉林大学化学学院,吉林 长春 130021
  • 折叠

摘要

Abstract

Ionothermal synthesis is a new method for the preparation of metal-organic framework materials with novel topologies in past decades. The recent developments in the ionothermal synthesis of metal-organic frameworks are reviewed. Various methods of ionothermal synthesis were introduced and the influences of ionic liquid on frame structure,as well as the synthesis of chiral metal-organic frameworks under ionothermal condition,were discussed in detail. Moreover,the advantages and shortcomings of ionothermal synthesis were analyzed and compared with traditional hydrothermal/solvothermal synthesis , especially the structural differences of several classical metal-organic frameworks obtained from hydrothermal/solvothermal or ionothermal methods were compared. It was pointed out that the mechanism of the ionic liquids influencing the structures of the metal-organic frameworks needs further investigation.

关键词

离子液体/金属-有机骨架/复合材料/离子热/水热

Key words

ionic liquids/metal-organic frameworks/composites/ionothermal/hydrothermal

分类

化学化工

引用本文复制引用

肖冰心,刘杰,王双,井淑波..离子热合成金属-有机骨架材料最新研究进展[J].化工进展,2014,(9):2363-2371,9.

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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