化工进展Issue(10):2687-2692,6.DOI:10.3969/j.issn.1000-6613.2014.10.027
模板法合成碳酸钙研究进展
Progress of preparation of calcium carbonate with template method
摘要
Abstract
Calcium carbonate is one of most abundant biological minerals. Calcium carbonate with multi-morphologies and different polymorphs can be used in different fields,including printing, ceramics,paints,and medicine. The template method is preferable to other approaches for synthesis of calcium carbonate,as its morphology and polymorph can be effectively controlled by simply altering the nature of template and preparation conditions. This paper reviews the development in preparation of calcium carbonate by using small molecule,natural macromolecule,gel,microemulsion and polymer as soft templates. The synthesis of calcium carbonate by using hard template is also described. The main development directions and problems in preparing calcium carbonate are analyzed by comparing the advantages and disadvantages of various matrixes. Finally,preparation of calcium carbonate and other biomaterials with the template method is prospected. The mechanism of synthesis of calcium carbonate with the template method,and using electrochemistry and other modern technology to improve the technology of controlling polymorphs and morphologies of calcium carbonate should be focused in the future.关键词
凝胶/表面活性剂/有机化合物/碳酸钙/模板法Key words
gels/surfactants/organic compounds/calcium carbonate/template method分类
通用工业技术引用本文复制引用
陈彰旭,辛梅华,李明春,陈晓东..模板法合成碳酸钙研究进展[J].化工进展,2014,(10):2687-2692,6.基金项目
国家自然科学基金青年科学基金(21103095,21206079)、福建省自然科学基金(2012J01396)、福建省高校服务海西建设重点项目(2009HX11)及福建省教育厅A类项目(JA12288)。 ()