化工进展Issue(11)：2941-2946,6.DOI:10.3969/j.issn.1000-6613.2014.11.020
钛系催化剂合成聚异戊二烯橡胶的研究进展
Development of titanium catalyst for cis-1,4-polyisoprene rubber
摘要
Abstract
The performance of isoprene rubber synthesized by the titanium catalyst is comparable to that of natural rubber. The paper is aimed to introduce the domestic and abroad developments of cis-1,4-polyisoprene rubber,and to summarize the influence factors of kinetic behavior for the polyisoprene polymerization and the content of cis-1,4-polyisoprene configuration in the microstructure of rubber synthesized by titanium catalyst. An overview on the synthesis methods of cis-1,4-polyisoprene by titanium catalyst is conducted , and the developing trend for titanium cis-1,4-polyisoprene rubber is prospected. It can be concluded that developing a cheap titanium catalysis system is an inevitable trend in the synthesis of isoprene rubber,developing titanium high cis-1,4-polyisoprene should be the prime choice for polyisoprene synthesis industry. Some existent problems and possible research subjects for the further improvement of synthesis cis-1,4-polyisoprene are suggested and discussed.关键词
合成/聚异戊二烯/橡胶/催化剂/配合物Key words
synthesis/polyisoprene/rubber/catalysts/complexes分类
化学化工引用本文复制引用
汪昭玮,于俊伟,刘晓暄..钛系催化剂合成聚异戊二烯橡胶的研究进展[J].化工进展,2014,(11):2941-2946,6.基金项目
茂名石化产业链延伸关键技术研发及产业化项目（2012A090300006）。 （）
