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污水出水有机物对臭氧氧化舒必利的影响

何欢 隋倩 吕树光 赵文涛 邱兆富

化工进展Issue(3):867-871,5.
化工进展Issue(3):867-871,5.DOI:10.16085/j.issn.1000-6613.2015.03.043

污水出水有机物对臭氧氧化舒必利的影响

Effects of effluent organic matter on ozonation of sulpiride

何欢 1隋倩 1吕树光 1赵文涛 2邱兆富1

作者信息

  • 1. 华东理工大学国家环境保护化工过程环境风险评价与控制重点实验室,上海 200237
  • 2. 同济大学环境科学与工程学院污染控制与资源化研究国家重点实验室,上海 200092
  • 折叠

摘要

Abstract

Ozonation can effectively remove emerging pollutants,such as pharmaceuticals and personal care products(PPCPs). However,the effectiveness may be affected by the matrix of wastewater effluent. In this study,the influence of effluent organic matter(EfOM)on the ozonation of sulpiride (SP),a regularly utilized antipsychotic drug,was investigate at two aspects of degradation and mineralization. And three representative model compounds,humic acid(HA),bovine serum albumin (BSA),and sodium alginate(AGS),were used to simulate the main constituents in EfOM. The results showed that ozonation can effectively remove SP concentration from aqueous solution,with the removal efficiency>85%within 8 min. However,SP couldn’t be mineralized completely,and TOC removal efficiency was <10% after 25min. The ozonation of SP was hindered by the added HA and BSA. With increasing concentrations of HA and BSA,the reaction rate of SP decreased and the mineralization of SP solution was enhanced. However,the influence of AGS on the ozonation of SP was minor at AGS concentrations of 0—3.0mg/(L TOC).

关键词

舒必利/氧化/溶液/腐殖酸/牛血清蛋白/海藻酸钠/反应动力学

Key words

sulpiride/oxidation/solution/humic acid/bovine serum albumin/sodium alginate/reaction kinetics

分类

资源环境

引用本文复制引用

何欢,隋倩,吕树光,赵文涛,邱兆富..污水出水有机物对臭氧氧化舒必利的影响[J].化工进展,2015,(3):867-871,5.

基金项目

国家自然科学基金(51208199)、中国博士后科学基金特别资助项目(2013T60429)及中央高校基本科研业务费专项项目。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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