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Pt/USY催化剂上FCC柴油加氢改质反应性能

迟克彬 赵震 田志坚 阎立军 马怀军 罗琛 刘坚

化工进展Issue(5):1300-1306,7.
化工进展Issue(5):1300-1306,7.DOI:10.16085/j.issn.1000-6613.2015.05.020

Pt/USY催化剂上FCC柴油加氢改质反应性能

Hydro-upgrading performance of FCC diesel oil on Pt/USY catalysts

迟克彬 1赵震 1田志坚 2阎立军 3马怀军 2罗琛 3刘坚1

作者信息

  • 1. 中国石油大学 北京 理学院,北京 102249
  • 2. 中国科学院大连化学物理研究所,辽宁大连 116023
  • 3. 中国石油石油化工研究院,北京 100195
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摘要

Abstract

Pt/USY,Pt/1.0K-USY and Pt/2.0K-USY hydro-upgrading catalysts were prepared. The typical structure and acidity of molecular sieves and catalysts were characterized by XRD,N2 absorption-desorption,NH3-TPD and Py-FT-IR. Then the hydro-upgrading performance of these catalysts was studied in a continuous down-flow fixed bed with stainless steel tubular reactor and refined FCC diesel oil was chosen as feedstock. The reaction results indicated that the activity of the catalysts mainly depended on their acid quantity,acid intensity,and acid distribution with the same Pt content and the similar pore structure. Suitable acidity was more favorable for the aromatic saturation and selective ring opening reaction. The diesel product meets national V Diesel standards.

关键词

分子筛/催化剂/FCC柴油/加氢/选择性开环

Key words

molecular sieves/catalyst/FCC diesel/hydrogenation/selective ring opening

分类

化学化工

引用本文复制引用

迟克彬,赵震,田志坚,阎立军,马怀军,罗琛,刘坚..Pt/USY催化剂上FCC柴油加氢改质反应性能[J].化工进展,2015,(5):1300-1306,7.

基金项目

中国石油天然气集团公司项目(2009A-3801-03,2014B-2312)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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