化工进展Issue(6):1699-1707,9.DOI:10.16085/j.issn.1000-6613.2015.06.031
功能化聚烯烃接枝共聚物的制备和应用研究新进展
New progress in synthesis and application of functionalized polyolefin graft copolymers
摘要
Abstract
The paper briefly describes the general significance of the synthesis of functional polyolefin graft copolymers. The recent progress in the design and the synthesis of functional polyolefin graft copolymers is reviewed. Three kinds of methods for the synthesis of functional polyolefin graft copolymers are introduced and compared with each other,i.e. I grafting onto,II grafting from:①living anionic polymerization,②boron oxide mediated free radical polymerization,③atom transfer radical polymerization(ATRP),④nitrogen oxide mediated free radical polymerization(NMRP),⑤reversible addition-fragmentation chain transfer polymerization,III grafting through. Then,the applications of polyolefin graft copolymers are briefly introduced. Finally,the prospect in functionalized polyolefin graft copolymers is foreseen,the research in new-pattern,high efficiency,practical methodologies and practical application are deemed to be the main research focuses of functional polyolefin graft copolymers.关键词
功能化/接枝共聚物/合成/聚合/聚烯烃Key words
functionalization/graft copolymers/synthesis/polymerization/ployolefin分类
化学化工引用本文复制引用
吴昊天,吕弛,姜涛,崔崑,马志..功能化聚烯烃接枝共聚物的制备和应用研究新进展[J].化工进展,2015,(6):1699-1707,9.基金项目
国家自然科学基金项目(21074146,21374130)。 ()