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功能化聚烯烃接枝共聚物的制备和应用研究新进展

吴昊天 吕弛 姜涛 崔崑 马志

化工进展Issue(6):1699-1707,9.
化工进展Issue(6):1699-1707,9.DOI:10.16085/j.issn.1000-6613.2015.06.031

功能化聚烯烃接枝共聚物的制备和应用研究新进展

New progress in synthesis and application of functionalized polyolefin graft copolymers

吴昊天 1吕弛 2姜涛 1崔崑 2马志1

作者信息

  • 1. 天津科技大学材料科学与化学工程学院,天津 300457
  • 2. 中国科学院有机功能分子合成与组装化学重点实验室,中国科学院上海有机化学研究所,上海 200032
  • 折叠

摘要

Abstract

The paper briefly describes the general significance of the synthesis of functional polyolefin graft copolymers. The recent progress in the design and the synthesis of functional polyolefin graft copolymers is reviewed. Three kinds of methods for the synthesis of functional polyolefin graft copolymers are introduced and compared with each other,i.e. I grafting onto,II grafting from:①living anionic polymerization,②boron oxide mediated free radical polymerization,③atom transfer radical polymerization(ATRP),④nitrogen oxide mediated free radical polymerization(NMRP),⑤reversible addition-fragmentation chain transfer polymerization,III grafting through. Then,the applications of polyolefin graft copolymers are briefly introduced. Finally,the prospect in functionalized polyolefin graft copolymers is foreseen,the research in new-pattern,high efficiency,practical methodologies and practical application are deemed to be the main research focuses of functional polyolefin graft copolymers.

关键词

功能化/接枝共聚物/合成/聚合/聚烯烃

Key words

functionalization/graft copolymers/synthesis/polymerization/ployolefin

分类

化学化工

引用本文复制引用

吴昊天,吕弛,姜涛,崔崑,马志..功能化聚烯烃接枝共聚物的制备和应用研究新进展[J].化工进展,2015,(6):1699-1707,9.

基金项目

国家自然科学基金项目(21074146,21374130)。 ()

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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