化工进展Issue(8)：2907-2915,9.DOI:10.16085/j.issn.1000-6613.2015.08.001
金属-有机骨架材料在气体膜分离中的研究进展
Progress of metal-organic framework-based membranes for gas separation
摘要
Abstract
Metal-organic frameworks (MOF) have potential applications in gas storage,separation, catalysis,drug delivery and optical devices due to their large surface area and free volume,adjustable pore surface and various structures. Among them,gas separation using MOF membranes and MOF-based mixed-matrix membranes (MMM) is considered as one of the most promising applications. So far,a large number of MOF have been synthesized in experiment. Computational chemistry,as a complement to experimental study,provides a convenient approach to screen the MOF candidates in a large scale and shortens the design and research period. This paper reviewed recent research progress in computational and experimental works on MOF-based membranes,which are mainly focused on the development of membranes with more abundant functionality and higher stability. However,it is still a great challenge to build the structure-property relationship using the computational chemistry method. Therefore,more efforts should be made to develop new concepts and methods to estimate the structure and performance of MOF membranes,and then to design membrane materials with high stability and low cost in the future.关键词
金属-有机骨架材料膜/气体分离/计算化学Key words
metal-organic framework membranes/gas separation/computational chemistry分类
化学化工引用本文复制引用
侯丹丹,刘大欢,阳庆元,仲崇立..金属-有机骨架材料在气体膜分离中的研究进展[J].化工进展,2015,(8):2907-2915,9.基金项目
国家重点基础研究发展计划（2013CB733503）、国家自然科学基金重点项目（21136001）及北京高等学校青年英才计划（YETP0486）项目。 （）
