化工进展Issue(8):3118-3123,6.DOI:10.16085/j.issn.1000-6613.2015.08.034
无机盐阴阳离子对稠油水包油型乳状液稳定性的影响
Effects of cationic/anionic electrolytes on the stability of heavy oil-in-water emulsions
摘要
Abstract
The effects of the concentrations of amphoteric/nonionic surfactant,inorganic/organic alkali and anionic/cationic electrolyte on the stability of heavy oil-in-water emulsions were researched. The experimental results show that the water separation rates first sharply decrease with the increase of surfactant concentrations,and then reduce gradually till the minimum value. The compositional alkali has an optimal concentration. Inorganic salts show a twofold effect on the stability of emulsions, increasing within the low salt concentration and decreasing above the high concentration of salt. The magnitude of the effects of univalent cations on water separation rates is as follows:KCl>NaCl>LiCl. And the influence of MgCl2 on the stability of emulsions is greater than that of CaCl2. The magnitude of the effects of univalent anions on water separation rates is as follows: NaCl>NaBr>NaI,and that of polyvalent is Na2SO4>NaCl>Na3PO4.关键词
两性表面活性剂/有机碱/单价盐/高价盐/乳状液稳定性Key words
amphoteric surfactant/organic alkali/univalent salt/polyvalent salt/emulsions stability分类
能源科技引用本文复制引用
孙娜娜,敬加强,丁晔,臧欣欣,邹亮..无机盐阴阳离子对稠油水包油型乳状液稳定性的影响[J].化工进展,2015,(8):3118-3123,6.基金项目
西南石油大学研究生创新基金暨“挑战杯”培育项目(CXJJ 2015030)。 ()