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Au/TiO2-B催化剂的CO低温氧化性能

王喜兵 纪拓 李力成 杨祝红 陆小华

化工学报Issue(5):1636-1643,8.
化工学报Issue(5):1636-1643,8.DOI:10.3969/j.issn.0438-1157.2014.05.012

Au/TiO2-B催化剂的CO低温氧化性能

Au/TiO2-B catalyst for low-temperature CO oxidation

王喜兵 1纪拓 1李力成 2杨祝红 1陆小华1

作者信息

  • 1. 南京工业大学材料化学工程国家重点实验室,江苏南京 210009
  • 2. 南京林业大学化学工程学院,江苏南京 210037
  • 折叠

摘要

Abstract

Exploring the catalytic performance of gold nanoparticles on the novel materials can effectively extend the application of gold catalyst. In this case, TiO2-B is used as a support to load gold nanoparticles for low-temperature CO oxidation. The TiO2-B was shaped in micron-scale fibers with length of 5-20μm, and the gold nanoparticles with size of~ 3 nm could be uniformly dispersed on the surface of TiO2-B. CO oxidation tests showed that the catalytic performance of gold nanoparticles was influenced by calcination temperature of TiO2-B which gave rise to the difference in gold dispersion and interaction between gold nanoparticles and support. The activity of gold deposited on the support with pure TiO2-B phase could exceed/match that on anatase nanopowders. Moreover, the gold nanoparticles activated at 300℃ showed the best CO oxidation performance, and the catalyst activated in oxidative atmosphere had a better catalytic performance than that in inert or reductive atmosphere.

关键词

TiO2-B/催化剂/纳米粒子/CO氧化/活化

Key words

TiO2-B/catalyst/nanoparticles/carbon monoxide oxidation/activation

分类

化学化工

引用本文复制引用

王喜兵,纪拓,李力成,杨祝红,陆小华..Au/TiO2-B催化剂的CO低温氧化性能[J].化工学报,2014,(5):1636-1643,8.

基金项目

国家重点基础研究发展计划项目(2013CB733503)。@@@@supported by the National Basic Research Program of China (2013CB733503) (2013CB733503)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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