化工学报Issue(6)：2186-2192,7.DOI:10.3969/j.issn.0438-1157.2014.06.032
石墨烯/聚苯胺复合阳极的制备及在MFC中的应用
Preparation and application of GR/PANI composite anode for MFC
摘要
Abstract
Graphene (GR) was synthesized from natural graphene powder by chemical oxidation-reduction method. Graphene/polyaniline (GR/PANI) film anode was prepared by electrochemical modification and used in fixed-bed microbial fuel cell (MFC) to examine the electrochemical performance of the prepared anodes. The prepared anodes were characterized by IR spectrum, X-ray diffraction (XRD) and field emission scanning electron microscope (FESEM), respectively. The electrochemical properties were studied by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Polyaniline evenly attached to graphene and GR/PANI film electrode had good reversibility, small resistance and good electrical conductivity. When the GR/PANI film anode was used in MFC, maximum output power density and open circuit voltage were up to 230.2 mW·m-2 and 834.6 mV respectively, 110.6% and 34.8% higher than those of unmodified anode. The resistance of GR/PANI film anode also decreased from 843.2Ωof the unmodified anode to 469.4Ω. The experiment results indicated that, the GR/PANI composite was an excellent electrode material, and the MFC with GR/PANI film anode showed good electricity production performance.关键词
膜/循环伏安法/交流阻抗法/固定床/燃料电池Key words
membranes/cyclic voltammetry/electrochemical impedance spectroscopy/fixed-bed/fuel cells分类
化学化工引用本文复制引用
何海波,王许云,白立俊,郭庆杰..石墨烯/聚苯胺复合阳极的制备及在MFC中的应用[J].化工学报,2014,(6):2186-2192,7.基金项目
山东省自然科学基金项目（ZR2013BM012）；国家自然科学基金项目（21276129）；山东省高等学校科研计划项目（J11LB62）。@@@@supported by the Natural Science Foundation of Shandong Province(ZR2013BM012)， the National Natural Science Foundation of China (21276129) and the Higher Educational Science and Technology Program of Shandong Province（J11LB62) （ZR2013BM012）
