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界面聚合中空纤维正渗透膜的制备和表征

李刚 王周为 李春霞 李雪梅 何涛 高从堦

化工学报Issue(8):3082-3088,7.
化工学报Issue(8):3082-3088,7.DOI:10.3969/j.issn.0438-1157.2014.08.032

界面聚合中空纤维正渗透膜的制备和表征

Preparation and characterization of hollow fiber forward osmosis membrane by interfacial polymerization

李刚 1王周为 2李春霞 3李雪梅 3何涛 3高从堦3

作者信息

  • 1. 中国海洋大学化学化工学院,山东 青岛 266003
  • 2. 中国科学院上海高等研究院,上海 201210
  • 3. 中国科学院上海高等研究院,上海 201210
  • 折叠

摘要

Abstract

Hollow fiber thin film composite forward osmosis membrane was prepared on the top of a tailor-made polysulfone hollow fiber support by interfacial polymerization. The relationship between casting parameters, membrane structure, and FO performance was studied. The results showed that the thickness of substrate membrane was one of the main factors affecting FO performance. The thicker membrane could cause more serious internal concentration polarization, leading to lower effective osmotic pressure across the membrane as well as water flux in the FO process. A thin film composite membrane with a thickness of 0.129 mm and force at breakage of 2.48 N was obtained. The FO membrane showed a water flux of 10.3 L·m-2·h-1 and a specific salt diffusion of 0.15 g·L-1.

关键词

正渗透/反渗透/中空纤维膜/内浓差极化/外浓差极化

Key words

forward osmosis/reverse osmosis/hollow fiber membrane/internal concentration polarization/external concentration polarization

分类

化学化工

引用本文复制引用

李刚,王周为,李春霞,李雪梅,何涛,高从堦..界面聚合中空纤维正渗透膜的制备和表征[J].化工学报,2014,(8):3082-3088,7.

基金项目

国家自然科学基金项目(21176119,51206114);上海市博士后科研资助计划项目(13R21421600)。the National Natural Science Foundation of China(21176119,51206114) and the Postdoc Funding of Shanghai (13R21421600) (21176119,51206114)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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