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改性聚乙烯填料CANON反应器的启动与运行

付昆明 张杰 曹相生 李冬 左早荣 王会芳

化工学报Issue(11):4406-4412,7.
化工学报Issue(11):4406-4412,7.DOI:10.3969/j.issn.0438-1157.2014.11.027

改性聚乙烯填料CANON反应器的启动与运行

Start-up of CANON reactor with modified polyethylene carrier and its performance

付昆明 1张杰 2曹相生 3李冬 3左早荣 3王会芳1

作者信息

  • 1. 北京建筑大学环境与能源工程学院,城市雨水系统与水环境省部共建教育部重点实验室,北京 100044
  • 2. 北京工业大学水质科学与水环境恢复工程北京市重点实验室,北京 100124
  • 3. 北京工业大学水质科学与水环境恢复工程北京市重点实验室,北京 100124
  • 折叠

摘要

Abstract

A CANON reactor with modified polyethylene carrier was started up by seeding sludge from another mature CANON reactor and using artificial inorganic ammonia-rich waste water as influent. To accelerate ANAMMOX bacteria cultivation, the start-up was under anaerobic conditions first to avoid dissolved oxygen inhibition on ANAMMOX bacteria, and then under aerobic conditions. The reactor was first under anaerobic conditions to start ANAMMOX process at room temperature [(20±5)℃] in first 300 days, however, total nitrogen removal load was only 0.12 kg·(m3·d)-1, which meant failure of ANAMMOX. When temperature was increased to 30℃, 30 days later, total nitrogen removal load was up to 0.23 kg·(m3·d)-1. Then anaerobic conditions was changed to aerobic conditions, and total nitrogen removal load was up to 1.01 kg·(m3·d)-1, while nitrogen removal efficiency was 77.61%, and average variation ratio of nitrate and nitrogen (3δNO--N/δTN) was 0.122, close to theoretical value 0.127, showing both good stability of nitritation and good nitrogen removal. Adopting the way of anaerobic stage first and then aerobic stage could not accelerate ANAMMOX bacteria cultivation as expected, and modified polyethylene carrier was not a suitable carrier to start ANAMMOX process under anaerobic conditions. However, once the reactor was successfully started up, aeration could be saved, though it might perform unstably. Modified polyethylene carrier was suggested to combine with UASB reactor to keep bacteria.

关键词

CANON工艺/改性聚乙烯/厌氧氨氧化/短程硝化/氨氮

Key words

CANON process/modified polyethylene/ANAMMOX/nitritation/ammonia

分类

资源环境

引用本文复制引用

付昆明,张杰,曹相生,李冬,左早荣,王会芳..改性聚乙烯填料CANON反应器的启动与运行[J].化工学报,2014,(11):4406-4412,7.

基金项目

国家自然科学基金项目(51308025);北京高等学校青年英才计划项目(YETP1649)。@@@@ supported by the National Natural Science Foundation of China (51308025), Beijing Higher Education Young Elite Teacher Project (YETP1649) (51308025)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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