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基于硫基循环抑制技术的危险废物焚烧炉二英排放的控制

吴海龙 林晓青 严密 陈彤 陆胜勇 李晓东 严建华

化工学报Issue(11):4593-4598,6.
化工学报Issue(11):4593-4598,6.DOI:10.3969/j.issn.0438-1157.2014.11.054

基于硫基循环抑制技术的危险废物焚烧炉二英排放的控制

Dioxins emission control from hazardous waste incinerator by SO2 recycling inhibition

吴海龙 1林晓青 2严密 3陈彤 3陆胜勇 4李晓东 3严建华3

作者信息

  • 1. 舟山市环境保护局,浙江舟山 316021
  • 2. 浙江大学热能工程研究所,能源清洁利用国家重点实验室,浙江杭州 310027
  • 3. 浙江大学热能工程研究所,能源清洁利用国家重点实验室,浙江杭州 310027
  • 4. 浙江工业大学能源与动力工程研究所,浙江杭州 310014
  • 折叠

摘要

Abstract

Sulfur acts as an effective inhibitor of dioxins formation, and such action has been proved in laboratory studies, but few studies in actual waste incinerators are reported. To control the emission of dioxins from hazardous waste incinerator (HWI) effectively, a new pilot scale system with SO2 recycling and fly ash thermal treatment from the bypass flue gas in an actual HWI (50t·d-1) was developed. An absorbent was used to realize SO2 recycling by which SO2absorption was conducted by the absorbent in the flue gas and SO2desorption was conducted in the low-temperature thermal treatment system. The capacity of SO2 accumulation and inhibition of dioxins synthesis of the system was studied, and it was found that the system could operate continuously. The system could maintain a high SO2concentration of 100 mg·m-3 after adding a certain amount of other S-compounds and reduce more than 80% of dioxins emission factor. Therefore, the SO2 recycling inhibition technology provides guidance for dioxin emission reduction during waste treatment, and the long-term stable operation of the system will play a key role in achieving low emission of dioxins, but some relevant parameters of the pilot system still need further optimization.

关键词

废物处理///合成/抑制/吸附/脱附/优化

Key words

waste treatment/dioxins/synthesis/inhibition/absorption/desorption/optimization

分类

能源科技

引用本文复制引用

吴海龙,林晓青,严密,陈彤,陆胜勇,李晓东,严建华..基于硫基循环抑制技术的危险废物焚烧炉二英排放的控制[J].化工学报,2014,(11):4593-4598,6.

基金项目

国家重点基础研究发展计划项目 ()

国家高技术研究发展计划项目(2012AA062803)。@@@@ supported by the National Basic Research Program of China (2011CB201503) and the National High Technology Research and Development Program of China (2012AA062803) (2011CB201503)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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