化工学报Issue(3)：1126-1132,7.DOI:10.11949/j.issn.0438-1157.20141219
活性焦孔结构演变规律及对脱硫性能的影响
Activated coke pore structure evolution and its influence on desulfuration
摘要
Abstract
Steam activation was used to prepare activated coke (AC). The pore structure generation process was controlled through the control of temperature and burning loss rate, and thus a special pore structure activated coke was prepared. The pore structure of the samples was characterized by N2 adsorption, and SO2 adsorption properties of different ACs were studied on the fixed bed system. In the preparation of AC, low temperature activation contributed to formation of micropore structure and improved desulfurization performance. Micropores were the main sites of active coke desulfurization reaction. Mesopores and macro-porous were the diffusion channels for molecules and store H2SO4. Microporous surface area could be used as a key indicator to evaluate desulfurization performance of active coke.关键词
活性焦/活化/孔结构/吸附性能Key words
activated coke/activation/pore structure/adsorption properties分类
资源环境引用本文复制引用
李阳,朱玉雯,高继慧,孙飞,雷鸣..活性焦孔结构演变规律及对脱硫性能的影响[J].化工学报,2015,(3):1126-1132,7.基金项目
国家自然科学基金-煤炭联合基金项目（51134015）。@@@@supported by the National Natural Science Foundation of China(51134015) （51134015）
