化工学报2015，Vol.66Issue(Z1)：38-44,7.DOI:10.11949/j.issn.0438-1157.20141907
含离子液体乙腈-正丙醇体系的等压汽液平衡
Isobaric vapor-liquid equilibrium for system of acetonitrile-n-propanol system containing ionic liquids
摘要
Abstract
Isobaric vapor liquid equilibrium (VLE) for the acetonitrile-n-propanol system containing different ionic liquids (ILs) at atmospheric pressure (101.3 kPa) was measured. The employed ionic liquids (ILs) are 1-benzyl-3-methylimidazolium chloride ([BzMIM][Cl]), 1-benzyl-3-methylimidazolium bromide ([BzMIM][Br]) and 1-hexyl-3-methylimidazolium bromide ([HMIM][Br]). The results showed that all the three ILs could enhance the relative volatility of acetonitrile ton-propanol. The order of the separation ability of ILs is [BzMIM][Cl] > [BzMIM][Br] > [HMIM][Br]. The ternary vapor liquid equilibrium experimental data werefitted with the nonrandom two-liquid (NRTL) model. It was demonstrated that NRTL model was suitable for the description of the ternary system of acetonitrile +n-propanol + IL.关键词
离子液体/乙腈/正丙醇/相对挥发度/汽液平衡Key words
ionic liquid/acetonitrile/n-propanol/relative volatility/vapor-liquid equilibrium分类
化学化工引用本文复制引用
李文秀,张琦,张亲亲,张志刚..含离子液体乙腈-正丙醇体系的等压汽液平衡[J].化工学报,2015,66(Z1):38-44,7.基金项目
国家自然科学基金项目(21076126).supported by the National Natural Science Foundation of China (21076126). （21076126）
