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Al-SBA-15介孔分子筛及其吸附脱氮研究

徐晓宇 沈健

化学工程Issue(12):30-33,38,5.
化学工程Issue(12):30-33,38,5.DOI:10.3969/j.issn.1005-9954.2014.12.007

Al-SBA-15介孔分子筛及其吸附脱氮研究

Al-SBA-15 mesoporous zeolite for adsorption and removal of nitrogen compounds

徐晓宇 1沈健1

作者信息

  • 1. 辽宁石油化工大学化学化工与环境学部,辽宁抚顺 113001
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摘要

Abstract

Al-SBA-15 mesoporous zeolite was synthesized by grafting , and the factors that affect the product were investigated, such as ratio of silica to alumina , calcination temperature, etc.The Al-SBA-15 mesoporous zeolite was characterized by XRD , BET, FT-IR, NH3-TPD.The comparative experiments on adsorptive removal of basic nitrogen compound were performed with the obtained product Al-SBA-15 and SBA-15 under the same conditions . The results show that Al-SBA-15 retains the SBA-15 highly-ordered two-dimensional hexagonal mesostructure .Al-SBA-15 has the better nitrogen adsorption capacity than SBA-15 .When calcination temperature is 550 ℃and the atomic ratio of silica to alumina is 50,the denitrification rate of Al-SBA-15 can reach the highest 68.02%,with the adsorption capacity of 30 .6 mg/g.

关键词

介孔分子筛/Al-SBA-15/碱性氮化物

Key words

mesoporous zeolite/Al-SBA-15/basic nitrogen compound

分类

能源科技

引用本文复制引用

徐晓宇,沈健..Al-SBA-15介孔分子筛及其吸附脱氮研究[J].化学工程,2014,(12):30-33,38,5.

化学工程

OA北大核心CSCDCSTPCD

1005-9954

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