杭州师范大学学报（自然科学版）Issue(6)：571-574,4.DOI:10.3969/j.issn.1674-232X.2014.06.002
三取代基膦配体促进RhCl3催化硅氢加成反应研究
The Promotion Effect of Triarylphosphine Ligand on RhCl 3 in Catalyzing Hydrosilylation Reaction
摘要
Abstract
The effects of a series of triarylphosphine with different substituents on RhCl3 in catalyzing hydrosilylation reaction were investigated . The results indicated that the tris (2‐methoxyphenyl) phosphine ligand promotes both the hydrosilylation reaction and the catalytic activity of RhCl 3 .When the ratio of tris (2‐methoxyphenyl) phosphine ligand and RhCl3 catalyst was 5∶1 in 100 ℃ ,the conversion rate was the highest ,and the catalytic effect was the best .关键词
膦配体/RhCl3/硅氢加成Key words
phosphine ligand/RhCl3/hydrosilylation分类
化学化工引用本文复制引用
牛崇拜,白赢,厉嘉云,彭家建,肖文军..三取代基膦配体促进RhCl3催化硅氢加成反应研究[J].杭州师范大学学报（自然科学版）,2014,(6):571-574,4.基金项目
国家自然科学基金青年科学基金项目（21203049，21303034）；浙江省自然科学基金项目（LY14B030007）． （）
