杭州师范大学学报（自然科学版）Issue(4)：342-347,6.DOI:10.3969/j.issn.1674-232X.2015.04.002
两个含2-（2-吡啶基）苯并咪唑的镍（Π）配合物的合成、晶体结构及表征
Synthesis,Crystal Structure and Properties of Two Ni (Ⅱ) Complexes with 2-(2-pyridyl)benzimidazole
范艳 1瞿志荣1
作者信息
- 1. 杭州师范大学有机硅化学及材料技术教育部重点实验室，浙江 杭州 311121
- 折叠
摘要
Abstract
The complex [Ni(PBIm)2Cl2 H2O]・ (C2 H5OH)(H2O) 1 is self‐assembled with NiCl2 ・ 6H2O and the ligands as the starting materials under acidic conditions by natural evaporation method ,and the complex [Ni(PBIm)Cl2 (CH3CH2OH)]2 2 (PBIm=2‐(2‐pyridyl)‐benzimidazole) is self‐assembled with the same raw materials by a hydrothermal method .The structures of the two complexes are characterized by X‐ray crystal diffraction . The results show that the complex 1 crystallizes in triclinic ,space group Pī,and the complex 2 crystallizes in monoclinic ,space group P21/c .Two complexes assemble into a 1D structure by the intermolecular hydrogen bonding interactions .The fluorescent property and thermal stability are also characterized ,the results show that complex 2 with higher thermal stability and the fluorescence intensity than complex 1 .关键词
2-(2-吡啶基)苯并咪唑/配合物/晶体结构/荧光Key words
2-(2-pyridyl)benzimidazole/complex/crystal structure/fluorescent分类
化学化工引用本文复制引用
范艳,瞿志荣..两个含2-（2-吡啶基）苯并咪唑的镍（Π）配合物的合成、晶体结构及表征[J].杭州师范大学学报（自然科学版）,2015,(4):342-347,6.
