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包覆硼氢化锂的表面结构表征及稳定性研究

舒远杰 丁小勇 陈智群 吴敏杰 刘宁 李亚南 翟连杰 徐露萍

火炸药学报Issue(2):30-34,5.
火炸药学报Issue(2):30-34,5.DOI:10.14077/j.issn.1007-7812.2015.02.006

包覆硼氢化锂的表面结构表征及稳定性研究

Study on Surface Structural Characterization and Stability of Coated Lithium Borohydride

舒远杰 1丁小勇 1陈智群 2吴敏杰 1刘宁 1李亚南 1翟连杰 1徐露萍1

作者信息

  • 1. 西安近代化学研究所,陕西 西安 710065
  • 2. 北京理工大学机电学院,北京 100081
  • 折叠

摘要

Abstract

To restrain the hygroscopicity of lithium borohydride and improve its stability during storage and application, olefin and polyester carbonate were used to coat on the surface of lithium borohydride by solvent evaporation method.The surface structure of coated lithium borohydride was studied by X-photoelectron energy spectra,diffuse reflection infrared spectra,roman spectra and scanning electron microscope,and its stability in the air was examined.The results show that the uniform coating layer is formed on the surface of coated lithium borohydride and the covered degree reaches to 82%.The defective surface can be effectively covered by the reaction product after exposed in the air for one hour to hinder the further reaction and make the relative stability degree increase by 50.7%.

关键词

分析化学/硼氢化锂/包覆/溶剂旋蒸法/吸湿性/结构表征/稳定性

Key words

analytical chemistry/lithium borohydride/coated/solvent evaporation method/hygroscopicity/struc-tural characterization/stability

分类

军事科技

引用本文复制引用

舒远杰,丁小勇,陈智群,吴敏杰,刘宁,李亚南,翟连杰,徐露萍..包覆硼氢化锂的表面结构表征及稳定性研究[J].火炸药学报,2015,(2):30-34,5.

基金项目

国家自然科学基金资助项目 ()

火炸药学报

OA北大核心CSCDCSTPCD

1007-7812

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