火炸药学报Issue(3)：64-68,5.DOI:10.14077/j.issn.1007-7812.2015.03.012
1-甲基-3，4-二硝基吡唑的合成、性能及晶体结构
Synthesis,Performance and Crystal Structure of 1-Methyl-3,4-dinitropyrazole
李永祥 1郭俊玲 1宋磊 2曹端林 1王建龙1
作者信息
- 1. 中北大学化工与环境学院，山西 太原 030051
- 2. 中国航天建设集团有限公司环境与安全设计研究院，北京 100071
- 折叠
摘要
Abstract
1-Methyl-3,4-dinitropyrazole(MDNP)was synthesized via methylation using 3,4-dinitropyrazole(DNP) as starting material.The structure of the target product was characterized by melting point determination,IR spectrometry and nuclear magnetic resonance etc.The single crystal of MDNP is cultured at room temperature and its structure was determined by a four-circle X-ray diffractometer.The thermal performance of MDNP was studied by DSC.The detonation velocity and detonation pressure of MDNP were calculated by Kamlet formula.Results show that the crystal is monoclinic,space group P 21/n with cell parameters of a =0.7263 nm,b =1.514 3 nm,c =1.0368 nm,V = 1.123 4 nm3 ,Z = 4,D = 1.480 g/cm3 ,F (0 0 0 )= 520.MDNP has good thermal stability.The detonation velocity and detonation pressure are 6.14km/s and 17.0GPa,respectively.It is an energetic material with potential application value.关键词
材料科学/3,4-二硝基吡唑/DNP/1-甲基-3,4-二硝基吡唑/MDNP/晶体结构/热稳定性Key words
material science/3,4-dinitropyrazole/DNP/1-methyl-3,4-dinitropyrazole/MDNP/synthesis/crystal structure/thermal stability分类
军事科技引用本文复制引用
李永祥,郭俊玲,宋磊,曹端林,王建龙..1-甲基-3，4-二硝基吡唑的合成、性能及晶体结构[J].火炸药学报,2015,(3):64-68,5.
