吉林大学学报（理学版）Issue(6)：1331-1336,6.DOI:10.13413/j.cnki.jdxblxb.2014.06.43
甲醛在聚苯胺载铂电极上的电催化氧化
Electrocatalytic Oxidation of Formaldehyde on Platinum Load on Polyaniline Electrode
摘要
Abstract
Polyaniline (PAn)was loaded on Ti-based metal electrode and platinum was loaded on polyaniline,and Pt/PAn/Ti was prepared by cyclic voltammetry (CV)and was characterized by SEM and CV.Electrocatalytic oxidation of formaldehyde on platinum load on polyaniline electrode was investigated by reseaching the electrocatalytic oxidation of formaldehyde on Pt/PAn/Ti electrode.The result shows that electrocatalytic oxidation of formaldehyde was related with the quantity of platinum microparticles. Platinum microparticles were dispersed better, showing bigger effective area. Compared with that of the Pt/Ti electrode with the same quantity of platinum deposited,the peak current of formaldehyde in the positive scanning was increased 2.3 times and oxidation potential was negatively shifted by about 40 mV on Pt/PAn/Ti electrode.The peak current of formaldehyde in the negative scanning was increased about 5 times and oxidation potential was negatively shifted by about 30 mV.At the same time,the result shows,too that the oxidation peak in the positive scanning was controlled by liquid phase mass transfer process and the oxidation peak in the negative scanning was controlled by adsorption behavior.关键词
钛电极/聚苯胺/循环伏安法/电催化氧化/甲醛Key words
Ti electrode/polyaniline/cyclic voltammetry/electrocatalytic oxidation/formaldehyde分类
化学化工引用本文复制引用
陈忠平,褚道葆,秦家成,宋常春,汪徐春,陈君华,过家好,张婷..甲醛在聚苯胺载铂电极上的电催化氧化[J].吉林大学学报（理学版）,2014,(6):1331-1336,6.基金项目
国家自然科学基金(批准号:20476001)和安徽省高校自然科学重点基金(批准号:KJ2013A079) （批准号:20476001）
