吉首大学学报(自然科学版)Issue(3):61-67,7.DOI:10.3969/j.cnki.jdxb.2015.03.014
钨/钼/磷钨/磷钼酸铋盐的催化性能
Catalytic Performance of Tungstate/Molybdate/Phosphotungstic/Phosphomolybdate Acid Bismuth Salt
摘要
Abstract
Bi2 WO6 ,Bi2 MoO6 ,BiPW12 O40 and BiPMo12 O40 catalysts were synthesized by hydrothermal and co‐precipitation method and characterized by IR ,UV‐vis ,FL ,SEM and X‐ray power diffraction (XRD) . The relationship between catalytic performance of catalysts and preparation conditions ,calcination tem‐perature and different substrates was explored .The best degradation of RhB (100 mL 4 mg/L) achieved 98 .1% over the unbaked Bi2 WO6 with the W/Bi molar rate 1∶2 ,which also had certain catalytic effect for degrading methyl orange and methylthionine chloride .The tungstate bismuth and molybdate bismuth catalysts had a good catalytic effect for degrading RhB ,methyl orange and methylthionine chloride as well .The catalytic performance of phosphomolybdate bismuth was poorer .关键词
光催化/铋系催化剂/罗丹明B/甲基橙/亚甲基蓝/有机污染物Key words
photocatalysis/bismuthic catalyst/RhB/methyl orange/methylthionine chloride/organic pol-lutants分类
化学化工引用本文复制引用
韩宇哲,王德华,李达达,王宏祥,蔡铁军,邓谦..钨/钼/磷钨/磷钼酸铋盐的催化性能[J].吉首大学学报(自然科学版),2015,(3):61-67,7.基金项目
湖南科技大学研究生创新基金项目(S130029);贵州省教育厅功能材料与资源化学特色重点实验室开放基金 ()