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钨/钼/磷钨/磷钼酸铋盐的催化性能

韩宇哲 王德华 李达达 王宏祥 蔡铁军 邓谦

吉首大学学报(自然科学版)Issue(3):61-67,7.
吉首大学学报(自然科学版)Issue(3):61-67,7.DOI:10.3969/j.cnki.jdxb.2015.03.014

钨/钼/磷钨/磷钼酸铋盐的催化性能

Catalytic Performance of Tungstate/Molybdate/Phosphotungstic/Phosphomolybdate Acid Bismuth Salt

韩宇哲 1王德华 1李达达 1王宏祥 1蔡铁军 1邓谦1

作者信息

  • 1. 湖南科技大学化学化工学院,湖南湘潭411201
  • 折叠

摘要

Abstract

Bi2 WO6 ,Bi2 MoO6 ,BiPW12 O40 and BiPMo12 O40 catalysts were synthesized by hydrothermal and co‐precipitation method and characterized by IR ,UV‐vis ,FL ,SEM and X‐ray power diffraction (XRD) . The relationship between catalytic performance of catalysts and preparation conditions ,calcination tem‐perature and different substrates was explored .The best degradation of RhB (100 mL 4 mg/L) achieved 98 .1% over the unbaked Bi2 WO6 with the W/Bi molar rate 1∶2 ,which also had certain catalytic effect for degrading methyl orange and methylthionine chloride .The tungstate bismuth and molybdate bismuth catalysts had a good catalytic effect for degrading RhB ,methyl orange and methylthionine chloride as well .The catalytic performance of phosphomolybdate bismuth was poorer .

关键词

光催化/铋系催化剂/罗丹明B/甲基橙/亚甲基蓝/有机污染物

Key words

photocatalysis/bismuthic catalyst/RhB/methyl orange/methylthionine chloride/organic pol-lutants

分类

化学化工

引用本文复制引用

韩宇哲,王德华,李达达,王宏祥,蔡铁军,邓谦..钨/钼/磷钨/磷钼酸铋盐的催化性能[J].吉首大学学报(自然科学版),2015,(3):61-67,7.

基金项目

湖南科技大学研究生创新基金项目(S130029);贵州省教育厅功能材料与资源化学特色重点实验室开放基金 ()

吉首大学学报(自然科学版)

1007-2985

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