净水技术Issue(6)：57-61,5.
表面分子印迹聚合物修饰 TiO2纳米管去除污水厂二级处理出水中雌激素试验
Experiment of Surface-Molecular-Imprinted and Polymer-Modified TiO2 Nanotubes for Estrogenic Chemicals Removal from Secondary Effluents of WWTP
摘要
Abstract
Surface-molecular-imprinted and polymer-modified TiO2 nanotube (S MIP TiO2 NTs)photocatalysts were fabricated, characterized,and tested for the removal of estrogenic pollutants from wastewater in this study for the first time. The results of scanning electron microscopy and Fourier-transform infrared spectroscopy show that average diameters of TiO2 NTs is 60 nm. The adsorption selectivity and photocatalytic activity of S MIP TiO2 NTs on template compound,which is compared with TiO2 NTs,are improved. Interestingly,S MIP TiO2 NTs exhibits higher adsorption intensity and photocatalytic selectivity at low concentrations (10~100μg/L)of E2 than at high concentrations (10 ~100 mg/L ). It is also found that some representative estrogenic chemicals could be selectively and rapidly removed from secondary effluents of municipal wastewater treatment plants using S MIP TiO2 NTs as photocatalysts. S MIP TiO2 NTs photocatalysts exhibit excellent regeneration characteristics.关键词
表面分子印迹/TiO2纳米管/雌激素/污水厂二级处理出水/污水回用Key words
surface molecular imprinting/TiO2 nanotube/estrogenic chemical/secondary effluent of WWTP/wastewater reclamation分类
资源环境引用本文复制引用
胡磊,张文龙,李轶..表面分子印迹聚合物修饰 TiO2纳米管去除污水厂二级处理出水中雌激素试验[J].净水技术,2014,(6):57-61,5.基金项目
国家水体污染控制与治理科技重大专项课题“太湖流域（江苏）控制单元水质目标管理与水污染物排放许可证实施”（№2012ZX07506002）；江苏省环保科研课题 （）
