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介孔氧化硅SBA-15对铯的吸附性能研究

江玲 龚霞 刘淑娟 马建国 罗明标 林海禄 丁志昆

江西农业大学学报Issue(2):363-368,6.
江西农业大学学报Issue(2):363-368,6.DOI:10.13836/j.jjau.2015056

介孔氧化硅SBA-15对铯的吸附性能研究

Sorption Characteristics of Cesium onto Mesoporous Silica SBA-15

江玲 1龚霞 2刘淑娟 1马建国 1罗明标 1林海禄 1丁志昆1

作者信息

  • 1. 东华理工大学 放射性地质与勘探技术国防重点学科实验室,江西 南昌 330013
  • 2. 江西农业大学 理学院,江西南昌 330045
  • 折叠

摘要

Abstract

SBA⁃15 is a porous silicon molecular sieve with large aperture and good thermal stability. It shows a promising prospect in the field of separation. In this study,mesoporous silica SBA⁃15 was synthesized and employed to investigate cesium sorption from aqueous solution. The synthesized SBA⁃15 was characterized with TEM and FTIR.The effects of pH,cesium initial concentration,adsorbent dosage,contact time and ionic strength on the sorption of cesium were studied in details.The experimental results showed that the sorption e⁃quilibrium could be achieved in 120 min at pH=6.The cesium sorption capacity was found to be 26.31 mg/g at the cesium initial concentration of 40 mg/L.The sorption isotherm and kinetics were investigated.The sorp⁃tion equilibrium data was well fitted with Langmuir isotherms,and the sorption kinetics was well defined by the Pseudo⁃first⁃order model.

关键词

SBA-15//吸附性能

Key words

SBA-15/cesium/sorption

分类

化学化工

引用本文复制引用

江玲,龚霞,刘淑娟,马建国,罗明标,林海禄,丁志昆..介孔氧化硅SBA-15对铯的吸附性能研究[J].江西农业大学学报,2015,(2):363-368,6.

基金项目

国家自然科学基金(21367001)、江西省教育厅基金(GJJ13471)、东华理工大学核资源与环境重点实验室开放基金(101119)、放射性地质与勘探技术国防重点学科实验室项目(2011RGET012,2011RGET015)和国家留学基金委2014国家公派高级研究学者及访问学者(含博士后)项目 ()

江西农业大学学报

OA北大核心CSCDCSTPCD

1000-2286

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