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石墨烯负载铂催化剂的制备及稳定性

卢立新 王新东

有色金属科学与工程Issue(3):40-44,5.
有色金属科学与工程Issue(3):40-44,5.DOI:10.13264/j.cnki.ysjskx.2015.03.008

石墨烯负载铂催化剂的制备及稳定性

Preparation and stability of patinum-loaded graphene catalyst

卢立新 1王新东1

作者信息

  • 1. 北京科技大学 冶金与生态工程学院,北京100083
  • 折叠

摘要

Abstract

Graphene oxide(GO) was prepared using grapheme powder as raw material. With GO and H2PtCl6 as precursor and ethylene glycol as solvent and reducing agent, composite catalyst Pt/Graphene was prepared by impregnation-reduction method. The as-prepared Pt/Graphene catalyst is characterized by X-ray powder diffraction, scanning electronmicroscopy and Raman spectroscopy. The results show that the Pt nanoparticles are dispersed into the graphene nanosheets by forming a face centered cubic crystal structure. The stability of the catalyst is evaluated by cyclic voltammetry and chronoamperometry. Compared with commercial catalyst, Pt/Graphene catalyst shows an improved electrochemical active area (ESCA) and electro catalytic activity. The Pt/Graphene catalyst has more favorable stability than the commercial catalyst.

关键词

石墨烯/铂催化剂/催化性能/稳定性

Key words

graphene/platinum catalyst/catalytic performance/stability

分类

化学化工

引用本文复制引用

卢立新,王新东..石墨烯负载铂催化剂的制备及稳定性[J].有色金属科学与工程,2015,(3):40-44,5.

基金项目

国家自然科学基金(91010002,50874008);国家基础研究计划973计划 ()

有色金属科学与工程

OACSTPCD

1674-9669

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