生物质化学工程Issue(3)：53-59,7.DOI:10.3969/j.issn.1673-5854.2014.03.011
纤维素快速热解生成左旋葡聚糖的机理研究进展
A Review on the Formation Mechanism of Levoglucosan during Fast Pyrolysis of Cellulose
摘要
Abstract
During the fast pyrolysis of cellulose at medium temperature, levoglucosan ( LG) is the most abundant product. Its formation pathway has gained extensive attention. This paper firstly concludes and compares the different LG formation pathways proposed by scholars from home and abroad. The formation mechanisms of LG are classified into 4 kinds, namely homolysis cleavage mechanism, heterolysis cleavage mechanism, mechanism via glucose and concerted decomposition mechanism. Drawbacks of analyzing reaction mechanism using experimental methods are also pointed out. The paper then summarizes the recent development, i. e. application of the Density Functional Theory ( DFT) . Its contents and results are compared in detail. Finally, future investigation in determination of the LG formation pathway is proposed.关键词
纤维素/快速热解机理/左旋葡聚糖Key words
cellulose/fast pyrolysis mechanism/levoglucosan分类
化学化工引用本文复制引用
张阳,胡斌,陆强,董长青,杨勇平..纤维素快速热解生成左旋葡聚糖的机理研究进展[J].生物质化学工程,2014,(3):53-59,7.基金项目
“十二五”国家科技支撑计划资助(2012BAD30B01) （2012BAD30B01）
苏州市科技计划项目(SYG201216) （SYG201216）
