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松香中枞酸型树脂酸在酸作用下变化规律的研究

古研 陈玉湘 赵振东 李冬梅 毕良武 王婧

林产化学与工业Issue(3):73-79,7.
林产化学与工业Issue(3):73-79,7.DOI:10.3969/j.issn.0253-2417.2015.03.013

松香中枞酸型树脂酸在酸作用下变化规律的研究

Variations Relationship of Abietic-type Acids under Acid Treatment

古研 1陈玉湘 1赵振东 2李冬梅 1毕良武 1王婧1

作者信息

  • 1. 中国林业科学研究院 林产化学工业研究所 生物质化学利用国家工程实验室 国家林业局林产化学工程重点开放性实验室 江苏省生物质能源与材料重点实验室,江苏 南京 210042
  • 2. 江苏强林生物能源材料有限公司,江苏 溧阳 213364
  • 折叠

摘要

Abstract

Slash pine ( P. elliottii) rosin and masson pine ( P. massoniana) rosin were treated using different type of acids at different time. The variation relationships of abietic-type acids were analyzed through the content changes of abietic-type acids and dehydroabietic acid. The results showed that isomerization took place among palustric acid,abietic acid and neoabietic acid,and at the same time dehydrogenation and decarboxylation occurred under acid treatment. The rates of isomerization,dehydrogenation and decarboxylation were affected by the type of acid,acid strength and treating time. With the increase of acid strength,the speed of isomerization,dehydrogenation and decarboxylation increased.

关键词

松香/枞酸型树脂酸/异构/脱氢

Key words

rosin/abietic-type acids/isomerization/dehydrogenation

分类

化学化工

引用本文复制引用

古研,陈玉湘,赵振东,李冬梅,毕良武,王婧..松香中枞酸型树脂酸在酸作用下变化规律的研究[J].林产化学与工业,2015,(3):73-79,7.

基金项目

国家质量监督检验检疫总局公益性行业科研专项(2012104006) (2012104006)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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