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炭基负载 V2 O5脱硝催化剂低温脱硝性能

张杨 刘兴利 王建峰 冯前伟 朱跃

热力发电Issue(10):62-65,69,5.
热力发电Issue(10):62-65,69,5.DOI:10.3969/j.issn.1002-3364.2014.10.062

炭基负载 V2 O5脱硝催化剂低温脱硝性能

Low-temperature SCR reactivity of the activated Carbon-supported vanadium oxide catalyst

张杨 1刘兴利 2王建峰 1冯前伟 1朱跃1

作者信息

  • 1. 华电电力科学研究院,浙江 杭州 310030
  • 2. 陕西华电蒲城发电有限责任公司,陕西 渭南 715501
  • 折叠

摘要

Abstract

Effects of reaction conditions on low-temperature SCR activity of the activated carbon-supported vanadium oxide (V2 O5/AC)catalyst were investigated in a fixed bed reactor.The results suggest that, compared with AC,the NO adsorption capacity of V2 O5/AC was enhanced a little while the NH 3 adsorp-tion capacity was significantly enhanced.The prepared V2 O5/AC catalyst had approximately 90% NOx re-duction rate at 250 ℃ and 36 000 L/(kg􀅰h)space velocity.Raising the temperature could promote the SCR process,but the ablation of AC was also accelerated.The SCR reactivity declined when H 2 O was add-ed into the simulated flue gas.Results of the transient response test suggest that O2 was essential to the SCR reaction.

关键词

脱硝/催化剂活性/V2 O5/活性炭

Key words

denitration/activity of catalyst/V2 O5/activated carbon/SCR

分类

资源环境

引用本文复制引用

张杨,刘兴利,王建峰,冯前伟,朱跃..炭基负载 V2 O5脱硝催化剂低温脱硝性能[J].热力发电,2014,(10):62-65,69,5.

基金项目

中国华电工程(集团)有限公司科技项目(CHEC-KJ-2011-39) (集团)

热力发电

OA北大核心CSTPCD

1002-3364

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