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变温镁基 CO2吸附剂的制备及应用 I. Na/Mg 物质的量比

左臣盛 周思宇 孙成志 王兴之 刘道胜 徐煇旼 朴容起 桂建舟 刘丹

燃料化学学报Issue(7):884-889,6.
燃料化学学报Issue(7):884-889,6.

变温镁基 CO2吸附剂的制备及应用 I. Na/Mg 物质的量比

Preparation and application of magnesium-based CO2 sorbent for temperature swing absorption I. Na/Mg mol ratio

左臣盛 1周思宇 1孙成志 1王兴之 1刘道胜 1徐煇旼 2朴容起 2桂建舟 1刘丹1

作者信息

  • 1. 辽宁石油化工大学 化学化工与环境学部,辽宁 抚顺 113001
  • 2. 韩国化学研究院,大田 305600
  • 折叠

摘要

Abstract

A series of magnesium-based CO2 absorbents with different Na/Mg molar ratios were prepared by precipitation method with Mg ( NO3 ) 2 and Na2 CO3 as raw materials, and characterized by various methods ( including XRD, SEM-EDS and DTG) to study the compositions, morphology and decomposition temperature and so on. The CO2 absorption performance was evaluated by temperature swing absorption-desorption dynamiccyclic tests to check the impact of Na/Mg molar ratio. It can be seen that optimum molecular ratio of Na to Mg is 8 . 15 , and the sorbents is homogeneous with lower decomposition temperature caused by small particles of the sample, and initial CO2 adsorption capacity can reach 9. 584%. Good recycling capability can be obtained aswell. Compared with the initial absorption capacity there was only . % decrease after recycles.

关键词

镁基吸附剂/二氧化碳/变温吸附

Key words

magnesium-based absorbent/CO2/temperature swing absorption

分类

化学化工

引用本文复制引用

左臣盛,周思宇,孙成志,王兴之,刘道胜,徐煇旼,朴容起,桂建舟,刘丹..变温镁基 CO2吸附剂的制备及应用 I. Na/Mg 物质的量比[J].燃料化学学报,2014,(7):884-889,6.

基金项目

国家自然科学基金(21103077) (21103077)

教育部新世纪优秀人才支持计划( NCET-11-1011) ( NCET-11-1011)

韩国教育科技部 KCRC 2020项目(2012M1A8A1912543) (2012M1A8A1912543)

天津市应用基础与前沿技术研究计划(13JCYBJC41600) (13JCYBJC41600)

辽宁省自然科学基金(201202123) (201202123)

辽宁省教育厅(L2012128)。 (L2012128)

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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