燃料化学学报Issue(8)：952-957,6.
液相中镍催化剂催化合成气甲烷化的初步研究
Syngas methanation over nickel catalyst in liquid-phase
摘要
Abstract
Unsupported metal nickel catalysts were prepared by liquid phase reduction method. The catalytic performance of the catalysts for syngas methanation were conducted in an autoclave using decalin as the hydrogen donor solvent at different operation conditions, such as temperature, mol ratio of H2/CO in feed gas. And the catalyst characterizations were conducted by means of XRD, SEM, H2-TPR. The results showed that the content of CH4 in the product gas was 89. 39% when 2% catalyst was used at 330℃, and the corresponding conversions of CO and H2 were 94. 56% and 92. 60%, respectively. When 4% catalyst was used, the CO conversion was further improved to more than 99% while the content of CH4 in the product gas exceeded 94. 26%. The best operation temperature of syngas methanation in liquid phase was 330 ℃and the optimum range of H2/CO mol ratio in feed was 2 . 20~2 . 67 .关键词
合成气甲烷化/十氢萘/供氢溶剂/镍催化剂Key words
syngas methanation reaction/decalin/hydrogen donation solvent/nickel catalyst分类
化学化工引用本文复制引用
黄国宝,王志青,李庆峰,黄戒介,房倚天..液相中镍催化剂催化合成气甲烷化的初步研究[J].燃料化学学报,2014,(8):952-957,6.基金项目
国家自然科学基金青年科学基金(21106173) （21106173）
中国科学院战略性先导科技专项(XDA07050100) （XDA07050100）
山西省青年科技研究基金(2013021007-2) （2013021007-2）
中国科学院山西煤炭化学研究所青年人才项目(2011SQNRC01)。 （2011SQNRC01）
