燃料化学学报Issue(11)：1351-1356,6.
氧化锌修饰的铁酸铜催化剂水煤气变换性能研究
Catalytic properties of ZnO-modified copper ferrite catalysts in water-gas shift reaction
摘要
Abstract
The catalytic properties of ZnO-modified copper ferrite in water-gas shift ( WGS) reaction were evaluated between 250 and 400℃.The Zn2.5-Cu/Fe (modified by 2.5%ZnO) showed high catalytic activity.The catalyst was characterized with XRD, SEM, H2-TPR and CO2-TPD techniques and N2 sorption experiment.It was shown that intro ducit on of pa proprita e amounts of ZnO transformed the CuFe2 O4 from the tetrahedral crystalline phase to the cubic, enhanced the CuFe2 O4 reducibility, and increased the amount of weak and medium basic sites.As a consequence, the interaction between copper and iron species was improved andt he catalytic activity was increased.关键词
水煤气变换反应/铁酸铜催化剂/氧化锌修饰/还原性/碱性位点Key words
WGS rae ction/copperf erir te/ZnO m do ification/r educibility/b asicity分类
化学化工引用本文复制引用
林性贻,张勇,李汝乐,詹瑛瑛,陈崇启,殷玲..氧化锌修饰的铁酸铜催化剂水煤气变换性能研究[J].燃料化学学报,2014,(11):1351-1356,6.基金项目
Supported by National Engineering Research Center of Chemical Fertilizer Catalysts， Fuzhou University． （）
