燃料化学学报Issue(11)：1394-1399,6.
氨基酸功能化磷钨酸盐的制备及其催化氧化脱硫性能
Prepartion of amino acid functionalized heteropolyacid salt and its catalytic performance for oxidation desulfurization of model oil
李佳慧 1胡嘉 1赵荣祥 1李秀萍2
作者信息
- 1. 辽宁石油化工大学 化学化工与环境学部石油化工学院，辽宁 抚顺 113001
- 2. 辽宁石油化工大学 化学化工与环境学部化学与材料科学学院，辽宁 抚顺 113001
- 折叠
摘要
Abstract
A new amino-acid functionalized heteropoly tungstate ([Ala]3PW) was prepared with alanine and phosphotungstic acid as raw materials.The structure of [ Ala ] 3 PW was characterized by XRD, FT-IR.The removal of dibenzothiophene ( DBT ) in model oil was studied by using [ Ala ] 3 PW as catalysts, hydrogen peroxide as oxidant and imidazolium tetrafluoroborate ( [ HMIM ] BF4 ) as the extractant.The influence of reca it on temperature, the amount of catalysts, the molar ratio of O/S(H2O 2/DBT), the amount of extracat nt and types of thioph ene on the desulfurization efficiency were investgi ated.The results indicated that under the optimal reaction conditions of 10 mL model oil, 0.04 g of [Ala]3PW, O/S(mol ratio) =6, V([HMIM]BF4)/V(o il)=0.6, reaction temperature of 50 ℃na d reaction time of 180 min, removal of DBT was found tob e 98.2%.The catalyst could be recycled 4 times withotu a significant decreaes in activity.关键词
L-丙氨酸/磷钨酸/二苯并噻吩/脱硫Key words
alanine/phosphotungstic acid/dibenzothiophene/desulfurization分类
能源科技引用本文复制引用
李佳慧,胡嘉,赵荣祥,李秀萍..氨基酸功能化磷钨酸盐的制备及其催化氧化脱硫性能[J].燃料化学学报,2014,(11):1394-1399,6.
