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丙烷在金属铁表面还原NO的实验研究

苏亚欣 陆哲惺 周皞 窦逸峰 邓文义

燃料化学学报Issue(12):1470-1477,8.
燃料化学学报Issue(12):1470-1477,8.

丙烷在金属铁表面还原NO的实验研究

Experimental study on NO reduction by propane over iron

苏亚欣 1陆哲惺 1周皞 1窦逸峰 1邓文义1

作者信息

  • 1. 东华大学 环境科学与工程学院,上海 201620
  • 折叠

摘要

Abstract

NO reduction by propane over iron was experimentally investigated in a one-dimensional temperature-programmed ceramic tubular reactor at 300 ~1 100 ℃ in N2 and simulated flue gas atmospheres.The NO reduction efficiencies by C3 H8 over iron were compared to that by methane.The results show that propane can effectively reduce NO to N2 over metallic iron.In N2 atmosphere, the NO reductoi n efficiency by propane over metallic iron is higher than that by methane at 500~900℃.More than 95%of NO is reduced by propane over metallic iron when the temperature is above 900℃, which is very close to that by methane.In simulated flue gas atmosphere, when the excessive air ratio is lower than 1.0, NO reduction by propane over iron exceeds 90%when the temperature is above 900℃.There is little di fferecn e in NO er duction whether there is a burnout for propane.At same conditions, NO reduction by propane over iron is higher than that by methane.The effect of SO2 on NO reduction by propane over iron is rather small and can be ignored.

关键词

NO还原/丙烷//甲烷

Key words

NO reduction/propane/iron/methane

分类

资源环境

引用本文复制引用

苏亚欣,陆哲惺,周皞,窦逸峰,邓文义..丙烷在金属铁表面还原NO的实验研究[J].燃料化学学报,2014,(12):1470-1477,8.

基金项目

国家自然科学基金(51278095)。 ()

燃料化学学报

OA北大核心CSCDCSTPCD

2097-213X

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