燃料化学学报Issue(4)：449-455,7.
Mn／Al－SBA－15的制备及吸附脱硫性能
Study on the preparation of Mn/Al-SBA-15 and its adsorpt ion desulfurization performance
纪桂杰 1张耀兵 1付宁宁 1唐磊 1刘鹏 1沈健1
作者信息
- 1. 辽宁石油化工大学 石化学院，辽宁 抚顺 113001
- 折叠
摘要
Abstract
Mn/Al-SBA-15 absorbent was synthe sized by impregnation using Al-SBA-15 prepa red by grafti ng method as sup port, manganese acetate asp recursor of active com ponent.The samples were characteriz ed by means of XRD, N2 ad sorption-desorption, NH3-TPD, Py-FTIR and XPS.The adsorbent was used for adsorption desulfurization of simulated gasoline.The optimum molar ratio of Al /Si was determined through combining characterization of samples and their desulfurization performance.The mechanism of adsorption desulfurization was proposed .The regenera tion prop erties were alsos tudied.The results showed thatw hen the molar ratio of Al/Si was 1 ∶45, the perf ormance of adsorbent wa s the best.The thiophene was adsorbed through acid-base reaction.The intr oduction of Al improved the stability and the regeneration of the adsorbent.关键词
噻吩/吸附/SBA-15/酸性/再生Key words
thiophene/adsorption/SB A-15/acidity/regeneration分类
化学化工引用本文复制引用
纪桂杰,张耀兵,付宁宁,唐磊,刘鹏,沈健..Mn／Al－SBA－15的制备及吸附脱硫性能[J].燃料化学学报,2015,(4):449-455,7.
