燃料化学学报Issue(4)：507-512,6.
聚苯胺炭复合载体制备的钯催化剂对甲酸的电催化氧化
Palladium catalysts supported by polyaniline carbon composite for formic acid electrooxidation
摘要
Abstract
The compo site support ( PAnC) with conductive polymer polyaniline and activated carbon are prepared.The catalytic performance of the Pd catalyst prepared with PAnC as a support is better than that of the catalyst prepared with activated carbon alone.In addition, the polyaniline carbon support (PAnC-S), which prepared with doping sodium dodecyl sulfate, owns lower charge transfer resistance, more mesoporous between 10 ~25 nm, larger specific surface area, 94.9 m2 /g.PAnC-S and PAnCh ave uniform particle sizes of ab ou t 30 nm.The Pd catal ysts prepared with PAnC-S and PAnC support have la rger electrochemical surface area, 84.7 and 62.6 m2 /g, respe ctively.Pd/PAnC-S and Pd/PAnC have higher activity and stability for for mic acid electro oxidation compared with the Pd/C.关键词
聚苯胺/甲酸/电催化/钯Key words
polyani line/for mic acid/el ectro-catalysi s/palladium分类
化学化工引用本文复制引用
邹璐,邓超,高颖,邬冰..聚苯胺炭复合载体制备的钯催化剂对甲酸的电催化氧化[J].燃料化学学报,2015,(4):507-512,6.基金项目
哈尔滨市科技创新人才专项资金（2010RFXXG018）；黑龙江省自然科学基金（B 201002）；黑龙江省高校科技创新团队建设计划（2011TD010）。 （）
