湿法冶金Issue(3)：213-217,5.DOI:10.13355/j.cnki.sfyj.2015.03.12
硫酸锰溶液碱化沉淀-焙烧法制备Mn3O4
Preparation of Mn3 O4 by Alkaline Precipitation-Calcination Process Using MnSO4 Solution
摘要
Abstract
The traditional preparation technology for Mn3 O4 has the problems of difficult process control and high pollutant .Combined with the advantages of the traditional liquid phase method and roasting method ,the new method that preparation of Mn3 O4 precursor using MnSO4 solution with despersant SDS by adding NaOH and preparation of Mn3 O4 through roasting the precursor was presented .The SEM and XRD analysis results show that under the experimental conditions for preparation of precursor of 1 .5 g/L SDS ,30 min reaction time ,60 ℃ reaction temperature and 300 r/min agitation rate ,uniform size particles about 100 nm can be obtained .The precursor composes of Mn(OH)2 ,MnOOH and Mn3 O4 .The best roasting temperature for preparing Mn3 O4 is 1 000 ℃ ,and Mn3 O4 product has tetragonal morphology with particle size of about 500 nm .关键词
硫酸锰溶液/四氧化三锰/前驱体/沉淀/焙烧/制备Key words
MnSO4 solution/Mn3O4/precursor/precipitation/calcinations/preparation分类
矿业与冶金引用本文复制引用
何克杰,罗炎,皮露,孙维义,丁桑岚,苏仕军..硫酸锰溶液碱化沉淀-焙烧法制备Mn3O4[J].湿法冶金,2015,(3):213-217,5.基金项目
国家自然科学基金资助项目（51374150，51304140）；四川省杰出青年基金资助项目（2011JQ0008）。 （）
