色谱Issue(4)：428-433,6.DOI:10.3724/SP.J.1123.2014.12018
环果糖色谱柱分离4组结构类似物
Separations of four groups of analogues on cyclofructan based columns
摘要
Abstract
The separations of the immunosuppressive reagents, capsaicinoids, vitamin E, cur⁃cumins on cyclofructan based stationary phases containing polystyrene supported native cyclo⁃fructan ( MCI Gel CRS100 ) , silica supported native cyclofructan ( Frulic N ) , silica supported isopropyl carbamate cyclofructan 6 ( Larihc P ) , silica supported R⁃naphthylethyl carbamate cyclofructan 6 ( Larihc RN) in normal phase HPLC mode were studied. From the investigation it showed that the column MCI Gel CRS100 was more suitable for the separation in normal phase than in hydrophilic interaction liquid chromatography. Derivatized cyclofructan stationary pha⁃ses, Larihc P and Larihc RN, showed better selectivities in comparison with the native cyclo⁃fructan stationary phases. Trifluoroacetic acid had less influence on resolution on cyclofructan based stationary phases in normal phase mode.关键词
环果糖/手性固定相/免疫抑制剂/维生素E/姜黄类化合物/辣椒碱Key words
cyclofructan/chiral stationary phase/immunosuppressive reagents/vitamin E/curcumins/capsaincinoids分类
化学化工引用本文复制引用
舒杨,高铭岑,易大为..环果糖色谱柱分离4组结构类似物[J].色谱,2015,(4):428-433,6.基金项目
国家自然科学基金项目（21105008）． （）
