中国石油大学学报（自然科学版）Issue(6)：173-178,6.DOI:10.3969/j.issn.1673-5005.2014.06.026
磺甲基酚醛树脂高温交联影响因素及控制方法
Influence factors and control methods of high-temperature crosslinking for sulphonated methyl phenolic resin
孙明波 1张敬春2
作者信息
- 1. 中国石油大学石油工程学院，山东青岛 266580
- 2. 山东大学胶体与界面化学教育部重点实验室，山东济南 250100
- 折叠
摘要
Abstract
The crosslinking mechanism and the associated influence factors of sulphonated methyl phenolic resin(SMP) at high temperatures were investigated. And two control methods of high-temperature crosslinking for SMP were proposed. It is found that the crosslinking is promoted with higher pH value, bigger salinity, higher reaction temperature and longer time. The solid nuclear magnetic resonance (NMR) and infrared results indicate that the crosslinking is a dehydration condensation reaction between the hydroxymethyl and active hydrogen on the phenol ring, which forms methylene bridge. Hence, oxidant and sulfonating agent can be utilized to reduce the hydroxymethyl amount on the phenol ring. In this way, the crosslinking re-action of SMP at high temperature could be controlled, through which the stability of polysulfonate drilling fluid at high tem-perature is improved.关键词
磺甲基酚醛树脂/交联/钻井液/羟甲基/固体核磁共振Key words
sulphonated methyl phenolic resin/crosslinking/drilling fluids/hydroxymethyl/solid NMR分类
化学化工引用本文复制引用
孙明波,张敬春..磺甲基酚醛树脂高温交联影响因素及控制方法[J].中国石油大学学报（自然科学版）,2014,(6):173-178,6.
