石油化工Issue(1):77-82,6.
丙烯酰胺/丙烯酸/N,N-二烯丙基油酰胺/N,N-二甲基二烯丙基氯化铵共聚物驱油剂的合成及其性能
Synthesis and Properties of Poly(AM-AA-DNDA-DMDAAC) as an Oil-Displacing Agent
摘要
Abstract
A novel water-soluble copolymer(PMADD) was synthesized from acrylamide(AM),acrylic acid(AA),N,N-diallyl oleic-amide(DNDA) and diallyl dimethyl ammonium chloride(DMDAAC), and characterized by means of FTIR and rheology. The properties of PMADD for enhanced oil recovery were studied. The results indicated that the optimum conditions for the synthesis of PMADD were:m(AM)∶m(AA)∶m(DMDAAC)∶m(DNDA) 5∶5∶0.3∶0.04,45℃,reaction system pH 7 and initiator dosage 0.3%(w)(based on the mass of the reactants). When the PMADD concentration was 2 000 mg/L,the apparent viscosity of its solution was 590.3 mPa·s. The viscosity retention rate of PMADD was 7.0% at the shear rate of 1 000 s-1. When the NaCl concentration was 12 000 mg/L,the viscosity retention rate of PMADD was 21.7%. The enhanced oil recovery(EOR) could increase by 12.46% when the concentration of PMADD was 2 000 mg/L and the salinity of simulated formation water was 5 200 mg/L.关键词
水溶性聚丙烯酰胺/聚合物驱油剂/原油采收率/N,N-二烯丙基油酰胺/N,N-二甲基二烯丙基氯化铵Key words
water-soluble polyacrylamide/polymer oil-displacing agent/enhanced oil recovery/N,N-diallyl oleic-amide/diallyl dimethyl ammonium chloride分类
能源科技引用本文复制引用
苟绍华,马永涛,何杨,夏鸿,张勤,周艳婷..丙烯酰胺/丙烯酸/N,N-二烯丙基油酰胺/N,N-二甲基二烯丙基氯化铵共聚物驱油剂的合成及其性能[J].石油化工,2015,(1):77-82,6.基金项目
四川省科技支撑计划项目(2012FZ0130);四川省省属高校科研创新团队建设计划项目(13TD0025);西南石油大学优秀人才支持计划(2014XJZ002)。 ()