石油化工高等学校学报Issue(2)：1-5,5.DOI:10.3969/j.issn.1006-396X.2014.02.001
聚（对苯二甲酸丁二醇酯-co-衣康酸丁二醇酯）的合成及表征
Synthesis and Characterization of Poly(Butylene Terephthalate-co-Butylene Itaconate)Copolyesters
摘要
Abstract
A series of biodegradable aliphatic/aromatic copolyesters-poly(butylene terephthalate-co-butylene itaconate)(PBTI) were synthesized by melt polycondensation using dimethyl terephthalate (DMT),1,4-butanediol(BD)and dimethyl itaconate (DI)as raw materials.The effects of polymerization time,temperature,as well as aliphatic/aromatic mole ratio on physical and thermal properties of the copolyesters were investigated.The structure of the copolyesters was studied by 1 H-NMR and FT-IR.DSC,TGA and GPC analysis clearly indicated that the molecular weight,glass-transition temperature and melting point were influenced by the ratio between DMT and DI in the final copolyesters.In addition,the effect of mole ratio between DMT and DI on the degradability of the copolyesters was studied.Results showed that the degradability of the copolyesters was gradually improved with the increase of the aliphatic units in the chain.关键词
衣康酸二甲酯/对苯二甲酸二甲酯/熔融缩聚法/共聚酯/生物可降解Key words
Dimethyl itaconate/Dimethyl terephthalate/Melt polycondensation/Copolyesters/Biodegradation分类
能源科技引用本文复制引用
肖志丹,王婷,王传兴,高传慧,朱来响,武玉民..聚（对苯二甲酸丁二醇酯-co-衣康酸丁二醇酯）的合成及表征[J].石油化工高等学校学报,2014,(2):1-5,5.基金项目
国家自然科学基金项目(21106075) （21106075）
青岛市基础研究-联合基金计划项目(12-1-4-3-(33)-jch)。 （12-1-4-3-(33）
