石油化工高等学校学报Issue(5)：28-32,38,6.DOI:10.3969/j.issn.1006-396X.2014.05.007
对甲氧基苯乙烯在离子液体中的正离子聚合
The Cationic Polymerization of p-Methoxystyrene in Ionic Liquid
摘要
Abstract
Cationic polymerization of p-Methoxystyrene (p-MOS)was achieved in imidazole phosphate ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim ][PF6 ]) with 2-chloro-2,4,4-trimethyl pentane (TMPCl ) and boron trifluoride (BF3 )as a initiating system at -10 ℃.The polymer molecular weight achieved 73 150 g/mol,and monomer conversion was more than 93.4%.The influence of reaction temperature and monomer concentrationon the polymerization was analyzed,and the molecular structure was characterized by 1 H-NMR.The results showed that there were two different ends structure of polymer,including chlorine end groups and double bond end groups,and the corresponding mechanism of cationic polymerization of p-Methoxystyrene in ionic liquid was proposed.关键词
咪唑磷酸盐类离子液体/对甲氧基苯乙烯/正离子聚合/绿色溶剂Key words
Imidazole phosphate ionic liquid/p-Methoxystyrene/Cationic polymerization/Green solvent分类
化学化工引用本文复制引用
宋雪超,伍一波,郭文莉,李树新..对甲氧基苯乙烯在离子液体中的正离子聚合[J].石油化工高等学校学报,2014,(5):28-32,38,6.基金项目
国家自然科学基金(51373026) （51373026）
国家重点基础研究发展计划(2012CB626811)。 （2012CB626811）
