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一种纯疏水缔合凝胶的制备及性能研究

杨思羽 石晓 安会勇 孟雪

石油化工高等学校学报Issue(6):16-19,4.
石油化工高等学校学报Issue(6):16-19,4.DOI:10.3969/j.issn.1006-396X.2014.06.004

一种纯疏水缔合凝胶的制备及性能研究

Preparation and Charaction of a Purely Hydrophobically Associating Hydrogels

杨思羽 1石晓 1安会勇 1孟雪2

作者信息

  • 1. 辽宁石油化工大学,辽宁抚顺 113001
  • 2. 中国石油抚顺石化公司石油二厂,辽宁抚顺 113000
  • 折叠

摘要

Abstract

A purely hydrophobically associating hydrogels were synthesized by the free radical copolymerization of acrylamide (AM)and dimethyldodecyl (2-acrylamidoethyl)ammonium bromide (AMQC1 2 )in water (named AQ-gels ).Tensile and compressive results showed that AQ-gels exhibited excellent mechanical properties.The tensile and compressive strengths were increased with the increment of monomer concentration and hydrophobe content.The tensile and compressive strengths of AQ-2.5-20 were about 250 kPa and 14 MPa,respectively.It should be noted that AQ-gels possessed both high strength and high toughness,which was validated by the tensile breaking elongation of 1 850% and compressive breaking elongation of 94%. Furthermore, AQ-gels had excellent elastic recoverability because the shapes and mechanical properties recovered instantaneously when the added force disappeared.

关键词

疏水缔合凝胶/拉伸强度/压缩强度/断裂伸长率/弹性回复

Key words

Hydrophobically associating hydrogel/Tensile strength/Compressive strength/Breaking elongation/Elastic recovery

分类

化学化工

引用本文复制引用

杨思羽,石晓,安会勇,孟雪..一种纯疏水缔合凝胶的制备及性能研究[J].石油化工高等学校学报,2014,(6):16-19,4.

基金项目

国家级大学生创新创业训练计划(201210148008)。 (201210148008)

石油化工高等学校学报

OACSTPCD

1006-396X

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