石油化工高等学校学报Issue(1)：12-15,4.DOI:10.3969/j.issn.1006-396X.2015.01.003
聚（对苯二甲酸丁二醇酯-co-衣康酸丁二醇酯）的改性
Modification of Poly(Butylene Terephthalate-co-Butylene Itaconate)Copolyesters
摘要
Abstract
A series of copolyesters-poly (butylene terephthalate-co-butylene itaconate)(PBTI)were synthesized by melt polycondensation from dimethyl itaconate (DI),1,4-butanediol (BD)and dimethyl terephthalate (DMT).On this basis, hydrophilic diol(PEG)was selected as comonomer component to react with DI,DMI and BD via direct melt polycondensation. A series of degradable aliphatic-aromatic copolyesters (PBTIG) with different PEG molecular weight and content were synthesized.Hydrolytic degradation results demonstrated that with the increase of the itaconic acid content,the degradation rate was speeded up,andthe hydrophilic PEG significantly increased the degradation rate of the copolyesters.The hydrolysis experiments showed that after 1 60 h,the residual of the PBTI was 91.35%,while,the residual amount is only 81.20% after adding hydrophilic PEG.The degradation rate was increased by 1 1 7.34% than PBTI.关键词
衣康酸二甲酯/对苯二甲酸二甲酯/聚乙二醇/降解性能Key words
Dimethyitaconate/Dimethyl terephthalate/Polyethylene glycol/Degradation property分类
能源科技引用本文复制引用
王晓红,郭方荣,高传慧,朱来响,张欣华,武玉民..聚（对苯二甲酸丁二醇酯-co-衣康酸丁二醇酯）的改性[J].石油化工高等学校学报,2015,(1):12-15,4.基金项目
山东省博士后创新专项资助项目(201003052) （201003052）
青岛市基础研究-联合基金计划项目(12-1-43-(33)-jch)。 （12-1-43-(33）
