石油化工高等学校学报Issue(1):78-84,7.DOI:10.3969/j.issn.1006-396X.2015.01.016
多支化两亲聚合物合成及其原油乳化作用研究
Synthesis of Multi-Sticker Amphiphilic Polmer and Reseach of Its Emulsifying Property
摘要
Abstract
The acrylamide/N-benzyl-N-n-hexadecylacrylamide/sodium acrylates terpolymer-P (AM/BHAM/NaA ) was synthesized using micellar polymerization and the synthetic scheme was optimized.The amphiphilic polymer has a critical aggregation concentration (CAC).Above CAC,P(AM/BHAM/NaA)forms network in aqueous solution.With the increase of polymer concentration,the hydrodynamic radius of it increases,and the apparent viscosity also increases.P (AM/BHAM/NaA)has good capability of crude oil emulsion.By studying the different concentrations of amphiphilic polymer on the properties of crude oil emulsion,it is found that with the increase of amphiphilic polymer concentration,the volume of network,formed by amphiphilic polymer in aqueous solution,increases and its emulsifying ability also is enhanced.关键词
多支化两亲聚合物/荧光探针/临界聚集浓度/流体力学半径/原油乳化Key words
Multi-sticker amphiphilic polymer/Fluorescence probe/Critical aggregation concentration/Hydrodynamics radius/Emulsifiability分类
能源科技引用本文复制引用
季岩峰,张向峰,胡雷雷..多支化两亲聚合物合成及其原油乳化作用研究[J].石油化工高等学校学报,2015,(1):78-84,7.基金项目
国家自然科学基金(21273286) (21273286)
中国石油大学(华东)研究生创新工程(YCX2014007)。 (华东)