天然气化工Issue(1)：30-35,77,7.
多组分气体吸附平衡预测的探究
Predication of adsorption equilibrium for multicomponent mixed-gases
孟凡超 1李超 1王亦修 1吕书玲 1王悦 1马正飞1
作者信息
- 1. 南京工业大学 材料化学工程国家重点实验室，江苏 南京 210009
- 折叠
摘要
Abstract
To solve the problem of adsorption equilibrium predication of multicomponent mixed-gases from the knowledge of adsorption isotherms for only single-component gases, a new model (Langmuir-Freundlich-Langmuir) considered the influence of adsorbent surface heterogeneity was developed for correlating the unary equilibria, which assumed that the adsorption behavior happened on two adsorption sites which were different from each other due to their different adsorption energy. In the predication of adsorption equilibria for the two-component mixed-gases, there were two boundary conditions caused by the different arrangement of two types of sites and only one case would turn out to be the correct correlation, and the prediction of adsorption equilibria for the three-component mixed-gas achieved good results. Several factors affecting the accuracy of prediction for the two-component mixed-gases were discussed from the selection of single-component model and the construction of multicomponent equilibrium prediction equation.关键词
多组分气体/吸附平衡/预测/模型Key words
multicomponent mixed-gas/adsorption equilibrium/predication/model分类
化学引用本文复制引用
孟凡超,李超,王亦修,吕书玲,王悦,马正飞..多组分气体吸附平衡预测的探究[J].天然气化工,2015,(1):30-35,77,7.
