生态环境学报Issue(6):1022-1026,5.
污泥好氧发酵过程中挥发性有机物(VOCs)污染风险研究
Contamination risk of volatile organic compounds during sludge composting
摘要
Abstract
Volatile organic compounds (VOCs) produced during sewage sludge aerobic composting is becoming an important secondary pollutant. The GC/MS method was used to analyze the components of VOCs at different positions in a Sludge Treatment Plant. A total of 19 VOCs were emitted during sewage sludge composting process. The main odor components, such as methanethiol, dimethyl sulfide and sulfide, have higher concentration than olfactory threshold at all four of the gas recovery points, and can do great harm to human beings. The concentration of total volatile organic compounds (TVOC) was 47.21 mg·m-3 inside the composting pile, and decreased to 1.73 mg·m-3 by a percentage of 96.3% after the emission to working area. Using the method of Maximum Incremental Reactivity to research the reactivity and Ozone Formation Potential of VOCs. VOCs components, such as alkanes, aromatic hydrocarbons, ketones, and olefin, have higher maximum ozone formation potential value, 1-butene and propylene have the maximum OFP, which were 947.70 μg·m-3 and 875.67 μg·m-3, respectively. Methyl mercaptan was an appropriate indicator to evaluate the emission of VOCs after a correlation analysis. The concentration of Methyl mercaptan in the researched plant was 0.04 mg·m-3, which was far lower than the limit of 2.5 mg·m-3 in GBZ 2-2002.关键词
污泥/堆肥/VOCs/污染风险Key words
sewage sludge/composting/VOCs/contamination risk分类
资源环境引用本文复制引用
马闯,赵占楠,赵继红,张宏忠,魏明宝,叶长明..污泥好氧发酵过程中挥发性有机物(VOCs)污染风险研究[J].生态环境学报,2014,(6):1022-1026,5.基金项目
国家水体污染控制与治理科技重大专项子课题(2012ZX07204-001);河南省重大公益科研招标项目(101100910300);河南省科技攻关项目(142102310063);河南省教育厅科学技术研究重点项目(14A610009);郑州轻工业学院博士科研基金项目 ()